Carbodiimides as fuel

In 2017, the Boekhoven Lab described the first example of a carbodiimide-fueled reaction cycle that we used to regulate molecular self-assembly (1). Practically simultaneously, the group of Scott Hartley published work using the same reaction cycle.(2)

The reaction cycles are versatile—it can regulate the supramolecular behavior of many different carboxylates.
It is simple—most laboratories have the needed ingredients: MES buffer, EDC, and a carboxylic acid.

As a result, the carbodiimide-driven reaction cycle and variations of it have been used by many other research teams worldwide to regulate self-assembly, phase separation, ratchets, motors, and many other supramolecular systems. Below, we curate a database with all the work using the carbodiimide-fueled reaction cycle and variations of it.

Feel free to contact us, if there is work missing.

References

1. M. Tena-Solsona, B. Rieß, R. K. Grötsch, F. C. Löhrer, C. Wanzke, B. Käsdorf, A. R. Bausch, P. Müller-Buschbaum, O. Lieleg, J. Boekhoven, Nature Communications 20178, 15895.

2. L. S. Kariyawasam, C. S. Hartley, J. Am. Chem. Soc. 2017, 139, 11949–11955.

Manuscripts that use carbodiimide fueled reaction cycles

AuthorsTitlePublicationYearDOILab
Kariyawasam, L.S.; Hartley, C.S.Dissipative assembly of aqueous carboxylic acid anhydrides fueled by carbodiimidesJACS201710.1021/jacs.7b06099Hartley
Tena-Solsona, M.; Rieß, B.; Grötsch, R.K.; Löhrer, F.C.; Wanzke, C.; et al.Non-equilibrium dissipative supramolecular materials with a tunable lifetimeNature Communications201710.1038/ncomms15895Boekhoven
Grötsch, R.K.; Angı, A.; Mideksa, Y.G.; Wanzke, C.; Tena‐Solsona, M.; et al.Dissipative self‐assembly of photoluminescent silicon nanocrystalsAngewandte Chemie201810.1002/anie.201807937Boekhoven
Rieß, B.; Wanzke, C.; Tena-Solsona, M.; Grötsch, R.K.; Maity, C.; et al.Dissipative assemblies that inhibit their deactivationSoft Matter201810.1039/c8sm00822aBoekhoven
Tena-Solsona, M.; Wanzke, C.; Riess, B.; Bausch, A.R.; Boekhoven, J.Self-selection of dissipative assemblies driven by primitive chemical reaction networksNature Communications201810.1038/s41467-018-04488-yBoekhoven
Bal, S.; Das, K.; Ahmed, S.; Das, D.Chemically fueled dissipative self‐assembly that exploits cooperative catalysisAngewandte Chemie201910.1002/ange.201811749Das
Grötsch, R.K.; Wanzke, C.; Speckbacher, M.; Angı, A.; Rieger, B.; et al.Pathway dependence in the fuel-driven dissipative self-assembly of nanoparticlesJACS201910.1021/jacs.9b02004Boekhoven
Kariyawasam, L.S.; Kron, J.C.; Jiang, R.; Sommer, A.J.; Hartley, C.S.Structure–property effects in the generation of transient aqueous benzoic acid anhydrides by carbodiimide fuelsThe Journal of Organic Chemistry201910.1021/acs.joc.9b02746Hartley
Zhang, B.; Jayalath, I.M.; Ke, J.; Sparks, J.L.; Hartley, C.S.; et al.Chemically fueled covalent crosslinking of polymer materialsChemical Communications201910.1039/c8cc09823aHartley; Konkolewicz
Cheng, M.; Qian, C.; Ding, Y.; Chen, Y.; Xiao, T.; et al.Writable and self-erasable hydrogel based on dissipative assembly process from multiple carboxyl tetraphenylethylene derivativeACS Materials Letters202010.1021/acsmaterialslett.9b00509Jiang; Wang
Dai, K.; Fores, J.R.; Wanzke, C.; Winkeljann, B.; Bergmann, A.M.; et al.Regulating chemically fueled peptide assemblies by molecular designJACS202010.1021/jacs.0c04203Boekhoven
Hossain, M.M.; Atkinson, J.L.; Hartley, C.S.Dissipative assembly of macrocycles comprising multiple transient bondsAngewandte Chemie202010.1002/anie.202001523Hartley
Jayalath, I.M.; Wang, H.; Mantel, G.; Kariyawasam, L.S.; Hartley, C.S.Chemically fueled transient geometry changes in diphenic acidsOrganic letters202010.1021/acs.orglett.0c02757Hartley
Kriebisch, B.A.K.; Jussupow, A.; Bergmann, A.M.; Kohler, F.; Dietz, H.; et al.Reciprocal coupling in chemically fueled assembly: a reaction cycle regulates self-assembly and vice versaJACS202010.1021/jacs.0c10486Boekhoven
Panja, S.; Dietrich, B.; Adams, D.J.Chemically Fuelled Self‐Regulating Gel‐to‐Gel TransitionChemSystemsChem202010.1002/syst.201900038Adams
Wanzke, C.; Jussupow, A.; Kohler, F.; Dietz, H.; Kaila, V.R.I.; et al.Dynamic vesicles formed by dissipative self‐assemblyChemSystemsChem202010.1002/syst.201900044Boekhoven
Borsley, S.; Leigh, D.A.; Roberts, B.M.W.A doubly kinetically-gated information ratchet autonomously driven by carbodiimide hydrationJACS202110.1021/jacs.1c01172Leigh
Dai, K.; Tena-Solsona, M.; Rodon Fores, J.; Bergmann, A.M.; Boekhoven, J.Morphological transitions in chemically fueled self-assemblyNanoscale202110.1039/d1nr04954bBoekhoven
Dodo, O.J.; Petit, L.; Rajawasam, C.W.H.; Hartley, C.S.; Konkolewicz, D.Tailoring lifetimes and properties of carbodiimide-fueled covalently cross-linked polymer networksMacromolecules202110.1021/acs.macromol.1c01586Hartley; Konkolewicz
Heckel, J.; Batti, F.; Mathers, R.T.; Walther, A.Spinodal decomposition of chemically fueled polymer solutionsSoft Matter202110.1039/d1sm00515dMathers; Walther
Heckel, J.; Loescher, S.; Mathers, R.T.; Walther, A.Chemically fueled volume phase transition of polyacid microgelsAngewandte Chemie202110.1002/ange.202014417Mathers; Walther
Jayalath, I.M.; Gerken, M.M.; Mantel, G.; Hartley, C.S.Substituent effects on transient, carbodiimide-induced geometry changes in diphenic acidsThe Journal of Organic Chemistry202110.1021/acs.joc.1c01385Hartley
Kretschmer, M.; Winkeljann, B.; Kriebisch, B.A.K.; Boekhoven, J.; Lieleg, O.Viscoelastic behavior of chemically fueled supramolecular hydrogels under load and influence of reaction side productsCommunications Materials202110.1038/s43246-021-00202-6Winkeljann; Lieleg
Kriebisch, C.M.E.; Bergmann, A.M.; Boekhoven, J.Fuel-driven dynamic combinatorial librariesJACS202110.1021/jacs.1c01616Boekhoven
Lang, X.; Thumu, U.; Yuan, L.; Zheng, C.; Zhang, H.; et al.Chemical fuel-driven transient polymeric micelle nanoreactors toward reversible trapping and reaction accelerationChemical Communications202110.1039/d1cc00726bHe; Zhao
Mondal, S.; Haldar, D.A transient non-covalent hydrogel by a supramolecular gelator with dynamic covalent bondsNew Journal of Chemistry202110.1039/d0nj05992gHaldar
Niebuur, B.-J.; Hegels, H.; Tena-Solsona, M.; Schwarz, P.S.; Boekhoven, J.; et al.Droplet formation by chemically fueled self-assembly: the role of precursor hydrophobicityThe Journal of Physical Chemistry B202110.1021/acs.jpcb.1c08034Boekhoven; Papadakis
Schnitter, F.; Bergmann, A.M.; Winkeljann, B.; Rodon Fores, J.; Lieleg, O.; et al.Synthesis and characterization of chemically fueled supramolecular materials driven by carbodiimide-based fuelsNature Protocols202110.1038/s41596-021-00563-9Boekhoven
Schnitter, F.; Boekhoven, J.A method to quench carbodiimide‐fueled self‐assemblyChemSystemsChem202110.1002/syst.202000037Boekhoven
Schwarz, P.S.; Laha, S.; Janssen, J.; Huss, T.; Boekhoven, J.; et al.Parasitic behavior in competing chemically fueled reaction cyclesChemical Science202110.1039/d1sc01106eBoekhoven; Weber
Schwarz, P.S.; Tebcharani, L.; Heger, J.E.; Müller-Buschbaum, P.; Boekhoven, J.Chemically fueled materials with a self-immolative mechanism: transient materials with a fast on/off responseChemical science202110.1039/d1sc02561aBoekhoven
Späth, F.; Donau, C.; Bergmann, A.M.; Kränzlein, M.; Synatschke, C.V.; et al.Molecular design of chemically fueled peptide–polyelectrolyte coacervate-based assembliesJACS202110.1021/jacs.1c01148Boekhoven
Würbser, M.A.; Schwarz, P.S.; Heckel, J.; Bergmann, A.M.; Walther, A.; et al.Chemically fueled block copolymer self‐assembly into transient nanoreactorsChemSystemsChem202110.1002/syst.202100015Walther; Boekhoven
Amano, S.; Esposito, M.; Kreidt, E.; Leigh, D.A.; Penocchio, E.; et al.Using catalysis to drive chemistry away from equilibrium: relating kinetic asymmetry, power strokes, and the Curtin–Hammett principle in Brownian ratchetsJACS202210.1021/jacs.2c08723Leigh; Penocchio
Bergmann, A.M.; Donau, C.; Späth, F.; Jahnke, K.; Göpfrich, K.; et al.Evolution and Single‐Droplet Analysis of Fuel‐Driven Compartments by Droplet‐Based MicrofluidicsAngewandte Chemie202210.1002/ange.202203928Göpfrich; Boekhoven
Binks, L.; Tian, C.; Fielden, S.D.P.; Vitorica-Yrezabal, I.J.; Leigh, D.A.Transamidation-driven molecular pumpsJACS202210.1021/jacs.2c06807Leigh
Borsley, S.; Kreidt, E.; Leigh, D.A.; Roberts, B.M.W.Autonomous fuelled directional rotation about a covalent single bondNature202210.1038/s41586-022-04450-5Leigh
Borsley, S.; Leigh, D.A.; Roberts, B.M.W.Chemical fuels for molecular machineryNature Chemistry202210.1038/s41557-022-00970-9Leigh
Borsley, S.; Leigh, D.A.; Roberts, B.M.W.; Vitorica-Yrezabal, I.J.Tuning the force, speed, and efficiency of an autonomous chemically fueled information ratchetJACS202210.1021/jacs.2c07633Leigh
Del Giudice, D.; Spatola, E.; Valentini, M.; Ercolani, G.; Di Stefano, S.Dissipative dynamic libraries (DDLs) and dissipative dynamic combinatorial chemistry (DDCC)ChemSystemsChem202210.1002/syst.202200023Ercolani; Di Stefano
Donau, C.; Späth, F.; Stasi, M.; Bergmann, A.M.; Boekhoven, J.Phase transitions in chemically fueled, multiphase complex coacervate dropletsAngewandte Chemie202210.1002/ange.202211905Boekhoven
Englert, A.; Vogel, J.F.; Bergner, T.; Loske, J.; von Delius, M.A ribonucleotide↔ phosphoramidate reaction network optimized by computer-aided designJACS202210.1021/jacs.2c05861von Delius
Hossain, M.M.; Jayalath, I.M.; Baral, R.; Hartley, C.S.Carbodiimide‐induced formation of transient polyether cagesChemSystemsChem202210.1002/syst.202200016Hartley
Panja, S.; Adams, D.J.Chemical crosslinking in ‘reactive’multicomponent gelsChemical Communications202210.1039/d2cc00919fAdams
Rodon-Fores, J.; Würbser, M.A.; Kretschmer, M.; Rieß, B.; Bergmann, A.M.; et al.A chemically fueled supramolecular glue for self-healing gelsChemical Science202210.1039/d2sc03691fBoekhoven
Schnitter, F.; Rieß, B.; Jandl, C.; Boekhoven, J.Memory, switches, and an OR-port through bistability in chemically fueled crystalsNature Communications202210.1038/s41467-022-30424-2Boekhoven
Schwarz, P.S.; Tena-Solsona, M.; Dai, K.; Boekhoven, J.Carbodiimide-fueled catalytic reaction cycles to regulate supramolecular processesChemical Communications202210.1039/d1cc06428bBoekhoven
Stasi, M.; Monferrer, A.; Babl, L.; Wunnava, S.; Dirscherl, C.F.; et al.Regulating DNA-hybridization using a chemically fueled reaction cycleJACS202210.1021/jacs.2c08463Boekhoven
Sun, J.; Vogel, J.; Chen, L.; Schleper, A.L.; Bergner, T.; et al.Carbodiimide‐Driven Dimerization and Self‐Assembly of Artificial, Ribose‐Based AmphiphilesChemistry–A European Journal202210.1002/chem.202104116von Delius
Xu, H.; Bai, S.; Gu, G.; Gao, Y.; Sun, X.; et al.Bioinspired self-resettable hydrogel actuators powered by a chemical fuelACS applied materials & interfaces202210.1021/acsami.2c13368Xuan; Wang
Zong, Z.; Zhang, Q.; Qiu, S.-H.; Wang, Q.; Zhao, C.; et al.Dynamic timing control over multicolor molecular emission by temporal chemical lockingAngewandte Chemie202210.1002/ange.202116414Qu
Zong, Z.; Zhang, Q.; Qu, D.-H.Dynamic Timing Control of Molecular Photoluminescent SystemsChemistry–A European Journal202210.1002/chem.202202462Zhang; Qu
Bai, S.; Wang, H.; Gu, G.; Gou, Y.; Zhou, X.; et al.Transient and directional growth of supramolecular hydrogels through reaction–diffusion-mediated self-assembly for dynamic wet gluingChemical Engineering Journal202310.1016/j.cej.2023.146125Wang; Guo
Bai, S.; Wang, H.; Gu, G.; Zhang, J.; Wei, L.; et al.Transient Assembly of Macroscopically Structured Supramolecular Hydrogels Driven by Shaped Chemical FuelsACS Materials Letters202310.1021/acsmaterialslett.3c00668Wang
Bauermann, J.; Bartolucci, G.; Boekhoven, J.; Weber, C.A.; Jülicher, F.Formation of liquid shells in active droplet systemsPhysical Review Research202310.1103/physrevresearch.5.043246Jülicher
Bergmann, A.M.; Bauermann, J.; Bartolucci, G.; Donau, C.; Stasi, M.; et al.Liquid spherical shells are a non-equilibrium steady state of active dropletsNature Communications202310.1038/s41467-023-42344-wWeber
Binks, L.; Borsley, S.; Gingrich, T.R.; Leigh, D.A.; Penocchio, E.; et al.The role of kinetic asymmetry and power strokes in an information ratchetChem202310.1016/j.chempr.2023.05.035Leigh
Chen, C.; Guan, Z.Precise Control of Dissipative Self‐assembly by Light and ElectricityChemistry–A European Journal202310.1002/chem.202300347Guan
Chen, J.; Wang, H.; Long, F.; Bai, S.; Wang, Y.Dynamic supramolecular hydrogels mediated by chemical reactionsChemical Communications202310.1039/d3cc04353cWang
Chen, X.; Kriebisch, B.A.K.; Bergmann, A.M.; Boekhoven, J.Design rules for reciprocal coupling in chemically fueled assemblyChemical Science202310.1039/d3sc02062bBoekhoven
Chen, X.; Soria-Carrera, H.; Zozulia, O.; Boekhoven, J.Suppressing catalyst poisoning in the carbodiimide-fueled reaction cycleChemical Science202310.1039/d3sc04281bBoekhoven
Chen, X.; Stasi, M.; Rodon-Fores, J.; Großmann, P.F.; Bergmann, A.M.; et al.A carbodiimide-fueled reaction cycle that forms transient 5 (4H)-oxazolonesJACS202310.1021/jacs.3c00273Boekhoven
Del Giudice, D.; Valentini, M.; Sappino, C.; Spatola, E.; Murru, A.; et al.Controlling the Conformation of 2‑Dimethylaminobiphenyls by Transient Intramolecular Hydrogen BondingThe Journal of Organic Chemistry202310.1021/acs.joc.2c02992Ercolani; Di Stefano
Edri, R.; Fisher, S.; Menor‐Salvan, C.; Williams, L.D.; Frenkel‐Pinter, M.Assembly‐driven protection from hydrolysis as key selective force during chemical evolutionFEBS letters202310.1002/1873-3468.14766Williams; Frenkel-Pinter
Gallagher, J.; Roberts, B.; Borsley, S.; Leigh, D.Dynamically accelerated catalysis through conformational selection by a molecular motorChem202310.1016/j.chempr.2023.10.019Leigh
Hou, X.-F.; Chen, X.; Wei, J.-H.; Xu, Y.; Chen, X.-M.; et al.Supramolecular dissipative self‐assembly systems: Approaches and applicationsResponsive Materials202310.1002/rpm.20230016Chen; Li
Häfner, G.; Müller, M.Reaction-driven assembly: controlling changes in membrane topology by reaction cyclesSoft Matter202310.1039/d3sm00876bMüller
Kriebisch, B.A.K.; Kriebisch, C.M.E.; Bergmann, A.M.; Wanzke, C.; Tena‐Solsona, M.; et al.Tuning the kinetic trapping in chemically fueled self‐assemblyChemSystemsChem202310.1002/syst.202200035Boekhoven
Kriebisch, C.; Burger, L.; Zozulia, O.; Stasi, M.; Floroni, A.; et al.Template-based information transfer in chemically fueled dynamic combinatorial librar-iesNat. Chem202310.21203/rs.3.rs-2710976/v1Boekhoven
Li, J.; Cui, Y.; Lu, Y.-L.; Zhang, Y.; Zhang, K.; et al.Programmable supramolecular chirality in non-equilibrium systems affording a multistate chiroptical switchNature Communications202310.1038/s41467-023-40698-9Liu
Li, J.; Wang, L.; Pan, C.; Yang, B.; Li, Y.Transient Biomacromolecular Nanoparticles for Labels with Self‐Erasable and Rewritable AbilityChemSystemsChem202310.1002/syst.202200036Li
Lo, S.; Ren, C.Z.-J.; Solís‐Muñana, P.; Chen, J.L.-Y.Dynamic Self‐assembled Supramolecular CatalystsSupramolecular Nanotechnology: Advanced Design of Self‐Assembled Functional Materials202310.1002/9783527834044.ch17Chen
Naik, S.; Torris, A.; Kiran, S.Construction and application of bionanomaterialsApplications of Multifunctional Nanomaterials202310.1016/b978-0-12-820557-0.00009-6Kiran
Pattloch, S.; Dzubiella, J.Mean-field models for the chemical fueling of transient soft matter statesSoft matter202310.1039/d3sm00742aDzubiella
Rajawasam, C.W.H.; Tran, C.; Weeks, M.; McCoy, K.S.; Ross-Shannon, R.; et al.Chemically fueled reinforcement of polymer hydrogelsJACS202310.1021/jacs.3c00668Hartley; Konkolewicz
Sangchai, T.; Al Shehimy, S.; Penocchio, E.; Ragazzon, G.Artificial molecular ratchets: tools enabling endergonic processesAngewandte Chemie202310.1002/ange.202309501Ragazzon
Singhania, A.; Kalita, S.; Chettri, P.; Ghosh, S.Accounts of applied molecular rotors and rotary motors: recent advancesNanoscale Advances202310.1039/d3na00010aGhosh
Skala, L.P.; Aguilar-Enriquez, X.; Stern, C.L.; Dichtel, W.R.Dissipative crystallization of ion-pair receptorsChem202310.1016/j.chempr.2022.12.010Dichtel
Späth, F.; Maier, A.S.; Stasi, M.; Bergmann, A.M.; Halama, K.; et al.The role of chemically innocent polyanions in active, chemically fueled complex coacervate dropletsAngewandte Chemie202310.1002/anie.202309318Boekhoven
Späth, F.; Maier, A.S.; Stasi, M.; Bergmann, A.M.; Halama, K.; et al.Die Rolle von unreaktiven Polyanionen in aktiven, chemisch regulierten komplexen KoazervatenAngewandte Chemie202310.1002/ange.202309318Boekhoven
Su, B.; Chi, T.; Ye, Z.; Xiang, Y.; Dong, P.; et al.Transient and dissipative host–guest hydrogels regulated by consumption of a reactive chemical fuelAngewandte Chemie202310.1021/scimeetings.3c10025Su
Tebcharani, L.; Akter, N.; Fan, D.; Lieleg, O.; Gibbs, J.M.; et al.Hydrolyzable emulsions as a dual release platform for hydrophobic drugs and DNAChemical Communications202310.1039/d3cc00888fBoekhoven
Zamberlan, F.An antidote for chemical reaction networksNature Catalysis202310.1038/s41929-023-01078-0Zamberlan
Al Shehimy, S.; Le, H.-D.; Amano, S.; Di Noja, S.; Monari, L.; et al.Progressive endergonic synthesis of Diels–Alder adducts driven by chemical energyAngewandte Chemie202410.1002/ange.202411554Ragazzon
Baretta, R.; Davidson-Rozenfeld, G.; Gutkin, V.; Frasconi, M.; Willner, I.Chemical and photochemical-driven dissipative Fe3+/Fe2+-ion cross-linked carboxymethyl cellulose gels operating under aerobic conditions: applications for transient controlled release and mechanical actuationJACS202410.1021/jacs.4c00625Frasconi; Willner
Bianco, S.; Adams, D.J.Stimuli‐responsive Structural Transformations of Peptide Supramolecular GelsPeptide Self‐Assembly and Engineering: Fundamentals, Structures, and Applications202410.1002/9783527841264.ch5Adams
Borsley, S.Membrane transport, molecular machines, and Maxwell’s DemonChemSystemsChem202410.1002/syst.202400004Borsley
Borsley, S.; Gallagher, J.M.; Leigh, D.A.; Roberts, B.M.W.Ratcheting synthesisNature Reviews Chemistry202410.1038/s41570-023-00558-yLeigh
Englert, A.; Majer, F.; Schiessl, J.L.; Kuehne, A.J.C.; von Delius, M.Acylphosphates as versatile transient species in reaction networks and optical catalyst screeningsChem202410.1016/j.chempr.2023.11.015von Delius
Fielden, S.D.P.Kinetically controlled and nonequilibrium assembly of block copolymers in solutionJACS202410.1021/jacs.4c03314Fielden
Fu, H.; Cao, N.; Zeng, W.; Liao, M.; Yao, S.; et al.Pumping Small Molecules Selectively through an Energy-Assisted Assembling Process at Nonequilibrium StatesJACS202410.1021/jacs.3c12228Zhou; Zhang
Gallagher, J.M.; Roberts, B.M.W.; Borsley, S.; Leigh, D.A.Conformational selection accelerates catalysis by an organocatalytic molecular motorChem202410.1016/j.chempr.2023.10.019Leigh
Gleeson, S.E.; Fink, Z.; Ashby, P.D.; Russell, T.P.; Helms, B.A.Transient structuring of liquids using dissipative interfacial assembliesMatter202410.1016/j.matt.2023.12.025Helms
Holtmannspötter, A.-L.; Machatzke, C.; Begemann, C.; Salibi, E.; Donau, C.; et al.Regulating nucleic acid catalysis using active dropletsAngewandte Chemie202410.1002/anie.202412534Boekhoven
Islam, M.; Baroi, M.K.; Das, B.K.; Kumari, A.; Das, K.; et al.Chemically fueled dynamic switching between assembly-encoded emissionsMaterials horizons202410.1039/d4mh00251bDas; Ahmed
Koppayithodi, S.; Ranasingh, P.; Singh, N.Life in Lab: Chemically Fueled Systems Chemistry for Emergent PropertiesChemSystemsChem202410.1002/syst.202400028Singh
Kriebisch, C.M.E.; Burger, L.; Zozulia, O.; Stasi, M.; Floroni, A.; et al.Template-based copying in chemically fuelled dynamic combinatorial librariesNature Chemistry202410.1038/s41557-024-01570-5Boekhoven
Olivieri, E.; Gallagher, J.M.; Betts, A.; Mrad, T.W.; Leigh, D.A.Endergonic synthesis driven by chemical fuellingNature Synthesis202410.1038/s44160-024-00493-wLeigh
Peddi, S.; Franklin, J.R.; Hartley, C.S.Observing the Transient Assembly and Disassembly of Carboxylic Anhydrides in the Organic Chemistry LaboratoryJournal of Chemical Education202410.1021/acs.jchemed.3c00731Hartley
Rajawasam, C.W.H.; Tran, C.; Sparks, J.L.; Krueger, W.H.; Hartley, C.S.; et al.Carbodiimide‐Driven Toughening of Interpenetrated Polymer NetworksAngewandte Chemie202410.1002/anie.202400843Konkolewicz
Saha, N.K.; Salvia, W.S.; Konkolewicz, D.; Hartley, C.S.Transient Covalent Polymers through Carbodiimide‐Driven AssemblyAngewandte Chemie202410.1002/ange.202404933Hartley
Salvia, W.S.; Mantel, G.; Saha, N.K.; Rajawasam, C.W.H.; Konkolewicz, D.; et al.Controlling carbodiimide-driven reaction networks through the reversible formation of pyridine adductsChemical Communications202410.1039/d4cc03633fKonkolewicz; Hartley
Späth, F.; Soria‐Carrera, H.; Stasi, M.; Sastre, J.; Kriebisch, B.A.K.; et al.Fuel‐Driven Dynamic Combinatorial Peptide LibrariesAngewandte Chemie202410.26434/chemrxiv-2024-3236vBoekhoven
Stasi, M.; Soria-Carrera, H.; Boekhoven, J.Synthesis goes uphill: Molecular ratchetsNature Synthesis202410.1038/s44160-024-00515-7Boekhoven
Wang, C.Catenane organocatalyst breaks the linear scaling limitation through conformational selectionCommunications Chemistry202410.1038/s42004-023-01088-wWang
Wang, H.; Bai, S.; Gu, G.; Zhang, C.; Wang, Y.Chemical Reaction Steers Spatiotemporal Self‐Assembly of Supramolecular HydrogelsChemPlusChem202410.1002/cplu.202400396Wang
Wang, L.; Yuan, J.; Hao, J.Transient self-assembly driven by chemical fuelsChemPhysMater202410.1016/j.chphma.2023.06.002Hao
Wenisch, M.; Braun, M.G.; Eylert, L.; Späth, F.; Poprawa, S.; et al.Towards Synthetic Life—Molecular Design of Complex Coacer-vates that Self-Divide202410.26434/chemrxiv-2024-035v4Boekhoven
Zambrano, P.; Chen, X.; Kriebisch, C.M.E.; Kriebisch, B.A.K.; Zozulia, O.; et al.Chemically driven division of protocells by membrane buddingJACS202410.1021/jacs.4c08226Boekhoven
Zozulia, O.; Kriebisch, C.M.E.; Kriebisch, B.A.K.; Soria‐Carrera, H.; Ryadi, K.R.; et al.Acyl phosphates as chemically fueled building blocks for self‐sustaining protocellsAngewandte Chemie202410.1002/ange.202406094Boekhoven
Ahmed, S.; Islam, S.A.; Baroi, M.K.; Das, B.K.; Pramanik, B.Chemically‐Fueled Time‐Gated Luminescent MetamorphosisAdvanced Materials202510.1002/adma.202509789Ahmed
Ashbridge, Z.; Reek, J.N.H.Transient allosteric regulation of catalysis by effector switching in a Pt2L4 cageAngewandte Chemie202510.1002/ange.202500214Reek
Bajpai, P.; Thulasiram, S.; Vanka, K.The critical helping hand of water: theory shows the way to obtain elusive, granular information about kinetic asymmetry driven systemsChemical Science202510.1039/d5sc03256cVanka
Dean Astumian, R.The role of kinetic asymmetry in chemical and thermodynamic couplingChemSystemsChem202510.1002/syst.202400066Dean Astumian
Enomoto, T.; Akimoto, A.M.; Yoshida, R.Chemically-fueled phase transition of a redox-responsive polymerScience and Technology of Advanced Materials202510.1080/14686996.2025.2494496Enomoto; Yoshida
Fracassi, A.; Seoane, A.; Brea, R.J.; Lee, H.-G.; Harjung, A.; et al.Abiotic lipid metabolism enables membrane plasticity in artificial cellsNature Chemistry202510.1038/s41557-025-01829-5Devaraj
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